Stadium: Olympic Athletic Center of Athens "Spiros Louis" Round: 3
| ITF M15 Sanxenxo MD | 2025/04/23 14:30 | Tsitsipas/Tsitsipas v Maia/Sau Franco | 4-6,1-5 |
| ATP Monte Carlo MD | 2025/04/09 12:25 | Tsitsipas/Tsitsipas v Cash/Glasspool | 1-6,6-7 |
| ATP Monte Carlo MD | 2025/04/06 16:15 | Tsitsipas/Tsitsipas v Harrison/King | 4-6,7-6,10-8 |
| ATP Dubai MD | 2025/02/25 11:45 | Haase/Jebens v Tsitsipas/Tsitsipas | 6-2,6-2 |
| ITF M15 Heraklion MD | 2024/11/14 13:15 | Demanet/Kalina v Tsitsipas/Tsitsipas | 6-4,4-6,10-8 |
| ITF M15 Heraklion MD | 2024/11/13 15:25 | Bolin/Nanobashvili v Tsitsipas/Tsitsipas | 3-6,4-6 |
| ITF M25 Heraklion MD | 2024/10/29 13:05 | Tsitsipas/Tsitsipas v Berrettini/Bertola | 3-6,6-7 |
| ATP Antwerp MD | 2024/10/16 14:00 | Haase/Pel v Tsitsipas/Tsitsipas | 6-3,6-4 |
| Challenger Bordeaux MD | 2025/05/17 10:35 | Matos/Melo v Bhambri/Galloway | 3-6,6-7 |
| Challenger Bordeaux MD | 2025/05/16 09:00 | Balaji/Reyes-Varela v Matos/Melo | 2-6,4-6 |
| Challenger Bordeaux MD | 2025/05/15 08:30 | Nouza/Rikl v Matos/Melo | 3-6,7-6,7-10 |
| ATP Rome MD | 2025/05/12 09:00 | Matos/Melo v Arends/Johnson | 2-6,3-6 |
| ATP Madrid MD | 2025/04/29 11:45 | Arevalo/Pavic v Matos/Melo | 6-3,6-4 |
| ATP Munich MD | 2025/04/16 12:45 | Schnaitter/Wallner v Matos/Melo | 3-6,6-4,10-5 |
| ATP Miami MD | 2025/03/22 23:35 | Arevalo/Pavic v Matos/Melo | 6-4,6-2 |
| ATP Rio de Janeiro MD | 2025/02/23 01:50 | Martinez/Munar v Matos/Melo | 2-6,5-7 |