[1] Rui-Xuan Wang 1-2 PSV [2] 2022-10-19 17:45
Stadium: Johan Cruijff ArenA Round: 13
Referee: Danny Makkelie Home Manager: Alfred Schreuder Away Manager: Ruud Van Nistelrooy
Head to Head
| Netherlands Super Cup | 2022/07/30 18:00 | Ajax v PSV | L | 3-5 |
| Netherlands Cup | 2022/04/17 16:00 | PSV v Ajax | L | 2-1 |
| Netherlands Eredivisie | 2022/01/23 13:30 | PSV v Ajax | W | 1-2 |
| Netherlands Eredivisie | 2021/10/24 14:45 | Ajax v PSV | W | 5-0 |
| Netherlands Super Cup | 2021/08/07 18:00 | Ajax v PSV | L | 0-4 |
| Netherlands Eredivisie | 2021/02/28 13:30 | PSV v Ajax | D | 1-1 |
| Netherlands Cup | 2021/02/10 19:00 | Ajax v PSV | W | 2-1 |
| Netherlands Eredivisie | 2021/01/10 15:45 | Ajax v PSV | D | 2-2 |
Home History
| Netherlands Eredivisie | 2022/10/16 18:00 | Ajax v Excelsior | W | 7-1 |
| UEFA Champions League | 2022/10/12 16:45 | Napoli v Ajax | L | 4-2 |
| Netherlands Eredivisie | 2022/10/08 14:30 | FC Volendam v Ajax | W | 2-4 |
| UEFA Champions League | 2022/10/04 19:00 | Ajax v Napoli | L | 1-6 |
| Netherlands Eredivisie | 2022/10/01 18:00 | Ajax v Go Ahead Eagles | D | 1-1 |
| Netherlands Eredivisie | 2022/09/18 14:45 | AZ v Ajax | L | 2-1 |
| UEFA Champions League | 2022/09/13 19:00 | Liverpool v Ajax | L | 2-1 |
| Netherlands Eredivisie | 2022/09/10 16:45 | Ajax v Heerenveen | W | 5-0 |
Away History
| Netherlands Eredivisie | 2022/10/16 12:30 | PSV v FC Utrecht | W | 6-1 |
| UEFA Europa League | 2022/10/13 19:00 | PSV v FC Zurich | W | 5-0 |
| Netherlands Eredivisie | 2022/10/09 14:45 | Heerenveen v PSV | W | 0-1 |
| UEFA Europa League | 2022/10/06 16:45 | FC Zurich v PSV | W | 1-5 |
| Netherlands Eredivisie | 2022/10/01 14:30 | Cambuur Leeuwarden v PSV | L | 3-0 |
| Netherlands Eredivisie | 2022/09/18 12:30 | PSV v Feyenoord | W | 4-3 |
| Netherlands Eredivisie | 2022/09/11 12:30 | PSV v RKC | W | 1-0 |
| UEFA Europa League | 2022/09/08 16:45 | PSV v Bodo/Glimt | D | 1-1 |
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