[11] Villarreal 5-2 Drzewiecki/Smola [18] 2021-12-03 10:00
Stadium: Estadio de la Ceramica Round: 4
Referee: Valentin Pizarro Gomez Home Manager: Unai Emery Away Manager: Javier Calleja Revilla
Head to Head
| Spain La Liga | 2021/04/21 19:00 | CD Alaves v Villarreal | L | 2-1 |
| Spain La Liga | 2020/09/30 17:00 | Villarreal v CD Alaves | W | 3-1 |
| Spain La Liga | 2020/01/25 17:30 | CD Alaves v Villarreal | W | 1-2 |
| Spain La Liga | 2019/10/25 19:00 | Villarreal v CD Alaves | W | 4-1 |
| Spain La Liga | 2019/03/02 15:15 | Villarreal v CD Alaves | L | 1-2 |
| Spain La Liga | 2018/10/28 17:30 | CD Alaves v Villarreal | L | 2-1 |
| Spain La Liga | 2018/02/10 12:00 | Villarreal v CD Alaves | L | 1-2 |
| Spain La Liga | 2017/09/17 10:00 | CD Alaves v Villarreal | W | 0-3 |
Home History
| Spain Copa del Rey | 2021/11/30 18:00 | Victoria CF v Villarreal | W | 0-8 |
| Spain La Liga | 2021/11/27 20:00 | Villarreal v Barcelona | L | 1-3 |
| UEFA Champions League | 2021/11/23 17:45 | Villarreal v Man Utd | L | 0-2 |
| Spain La Liga | 2021/11/20 13:00 | Celta Vigo v Villarreal | D | 1-1 |
| Spain La Liga | 2021/11/07 13:00 | Villarreal v Getafe | W | 1-0 |
| UEFA Champions League | 2021/11/02 20:00 | Villarreal v Young Boys | W | 2-0 |
| Spain La Liga | 2021/10/30 16:30 | Valencia v Villarreal | L | 2-0 |
| Spain La Liga | 2021/10/26 19:30 | Villarreal v Cadiz | D | 3-3 |
Away History
| Spain Copa del Rey | 2021/11/30 18:00 | Unami CP v CD Alaves | W | 0-3 |
| Spain La Liga | 2021/11/27 13:00 | CD Alaves v Celta Vigo | L | 1-2 |
| Spain La Liga | 2021/11/20 15:15 | Sevilla v CD Alaves | D | 2-2 |
| Spain La Liga | 2021/11/06 17:30 | CD Alaves v Levante | W | 2-1 |
| Spain La Liga | 2021/10/30 19:00 | Barcelona v CD Alaves | D | 1-1 |
| Spain La Liga | 2021/10/26 17:00 | CD Alaves v Elche | W | 1-0 |
| Spain La Liga | 2021/10/23 14:15 | Cadiz v CD Alaves | W | 0-2 |
| Spain La Liga | 2021/10/18 17:00 | CD Alaves v Real Betis | L | 0-1 |
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